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Scientific Reports:
April
2006:
Indoor Air Chemistry: Cleaning Agents, Ozone and Toxic Air Contaminants
(206 page PDF file)
Conclusions:
The study results indicate that, in California and elsewhere, elevated
inhalation exposures to air
pollutants can be expected to occur under some circumstances owing to
the use of common
cleaning products and air fresheners. Several of the products studied
contained and emitted
substantial amounts of a single TAC, 2-butoxyethanol. This
ethylene-based glycol ether was
found to be an active ingredient in six of the 21 products
characterized. The measured peak
concentrations of 2-butoxyethanol owing to the use of these products
were below relevant acute
exposure guidelines. However, modeled exposures for high-use scenarios
suggest that the
California acute (one-hour) exposure level of 14 mg m-3 might be
exceeded under some
circumstances. Also of potential concern are the terpenes and related
unsaturated organic
compounds. These constituents are widely used as solvents and as
scenting agents. Many
species in this class react rapidly with ozone, leading to the formation
of formaldehyde, a TAC
with a low chronic reference exposure level, and particulate matter, a
regulated pollutant class in
ambient air. Other oxidation products are also formed with unknown
toxicological properties
(e.g., hydroperoxides from linalool.) Thus, it appears that, when
compared with health-based
concentration guidelines and standards, the levels of 2-butoxyethanol,
formaldehyde and
particulate matter associated with the use of certain consumer products
can be high enough under
some circumstances to warrant further consideration. Further
consideration should also be given
to the toxicological properties of yet-to-be-evaluated oxidation
byproducts of ozone-terpene
chemistry.
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